Sterling will play as City on PlayStation 4 as he puts his FIFA skills to the test against a host of other Premier League players in a bid to be crowned champion.
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The prize fund is being donated to the #PlayersTogether initiative, which was created by Premier League players as a collective way of generating funds for the National Health Service and distributing them where they are needed most.
Our No.7 is participating alongside Wilfried Zaha (Crystal Palace), Trent Alexander-Arnold (Liverpool), Todd Cantwell (Norwich City), Ryan Fredericks (West Ham United) and Diogo Jota (Wolverhampton Wanderers).
The full line-up will be announced ahead of the draw for the tournament, which takes place on Monday 20 April and you can watch it live on Sky Sports Main Event from 9am.
The opening rounds will be played between Tuesday 21 and Friday 24 April, while the semi-finals and final will be televised live on Sky Sports Main Event at 3pm on Saturday 25 April.
City fans can keep an eye on how Sterling performs throughout the week, with all the action available to watch on the Premier League website, app, YouTube, Facebook and Twitter channels; Sky Sports YouTube and Twitch channels as well on the Football Daily YouTube channel.