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Nick Cushing's side will welcome the Primera División runners-up to the Academy Stadium in a 6:30pm BST kick-off, in a clash which will see striker Toni Duggan return to her former Club.
The two sides have never played each other but, as two of the Europe's best sides lock horns, the encounter promises to be an entertaining contest.
Cushing has often spoken of the importance of facing quality opposition in pre-season and as the Blues will have already faced Paris Saint-Germain, as well as Lyon in the inaugural Women's International Champions Cup, City will be more than ready for the 2018/19 campaign.
Ticket information will be released soon...